Bond-line structures, also called line-angle or skeletal structures are simple representations of organic molecules that will be used throughout your organic chemistry class. Understanding and being able to draw these structures is crucial.

In a bond-line structure, carbons are not shown. Instead, ends of the lines and lines coming together represent carbons. Hydrogens that are attached to carbons are not shown but implied. Look at the examples below to learn how to interpret bond-line structures.

Zigzag lines are used for carbon chains in bond-line structures. The end of the line and two lines coming together represent a carbon. Hydrogens are not shown. However, you have to know that every carbon wants to have four bonds. So, you can determine the number of hydrogens. For example, carbon 1 has one bond and that means it must be attached to three hydrogens. Carbon 2 has two bonds and must be attached to two hydrogens

bond line structure of butene

Double bonds are represented as two lines.

bond-line structure of 2-butyne

Triple bonds are a bit tricky. When you draw a triple bond, you have to draw it straight. The carbons on the triple bond and those attached to the triple bond must be straight but the rest of the carbons will be on a zigzag. Many students do not realize that the place where a triple bond starts represents a carbon (C2) and a place where it ends is also a carbon (C3). Keep that in mind when drawing triple bonds.

bond line structure of cyclohexane

Rings are also drawn using bond-line structures.

How To Draw Bond-Line Structures From Condensed Structures

  1. Convert your condensed formula into Lewis Dot Structure. If you need to review this, visit THIS PAGE.
  2. Number the carbons in your chain
  3. Follow the carbons in the Lewis structure to draw the bond-line structure. Remember to show chains of carbons as zigzags.
    Let’s look at some examples:
    Draw a bond-line structure for each of the following compounds

convert condensed structure into bond line structure

First, you need to convert the condensed structure into the Lewis structure to see what is bonded to what. Then, you can number the carbons in the chain and draw out the zigzag numbering carbons again. Carbon 2 is attached to a CH3 and carbon 3 is attached to an OH.

convert condensed structure into bond line structure

First, you will number the carbons and draw out the Lewis structure. Then number the carbons in the Lewis structure and draw out the zigzag. Don’t forget to include the double bond between carbon 1 and 2 and attach two CH3 groups to carbon 4.

convert condensed structure into bond line structure

First, you will number the carbons and draw out the Lewis structure. Notice there is a carboxylic acid functional group. Next draw out the zigzag and add double bond O and OH to the last carbon.

Mistakes to avoid when drawing Bond-Line Structures

Where there is a hill, draw your group UP, not down. When there is a valley, draw your group DOWN, not up.

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References:
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